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10

2 puntos
a
Formule o nombre los siguientes compuestos:1 pt
a.i
2-cloro-3-metilhex-1-eno0,2 pts
a.ii
Ácido butanoico0,2 pts
a.iii
meta-yodotolueno0,2 pts
a.iv
CHX3−CHX2−O−CHX2−CHX2−CHX3\ce{CH3}{-}\allowbreak\ce{CH2}{-}\allowbreak\ce{O}{-}\allowbreak\ce{CH2}{-}\allowbreak\ce{CH2}{-}\allowbreak\ce{CH3}0,2 pts
a.v
CHX3−CHX2−C≡N\ce{CH3-CH2-C#N}0,2 pts
b
Identifique cada una de las siguientes reacciones orgánicas:1 pt
b.i
CHX3−CHX2Cl+Na(CHX3−O)→CHX3−CHX2−O−CHX3+NaCl\ce{CH3}{-}\allowbreak\ce{CH2Cl} + \ce{Na(CH3-O)} \mathrel{\ce{->}} \ce{CH3}{-}\allowbreak\ce{CH2}{-}\allowbreak\ce{O}{-}\allowbreak\ce{CH3} + \ce{NaCl}0,2 pts
b.ii
(CHX3)X3CH+132 OX2→4 COX2+5 HX2O\ce{(CH3)3CH} + \ce{13/2 O2} \mathrel{\ce{->}} \ce{4CO2} + \ce{5H2O}0,2 pts
b.iii
CHX3−CHX2−C≡CH+HCl→CHX3−CHX2−CCl=CHX2\ce{CH3}{-}\allowbreak\ce{CH2}{-}\allowbreak\ce{C#CH} + \ce{HCl} \mathrel{\ce{->}} \ce{CH3}{-}\allowbreak\ce{CH2}{-}\allowbreak\ce{CCl}{=}\allowbreak\ce{CH2}0,2 pts
b.iv
CHX3−CHX2−CHX2−CH=CHBr+NaCN→CHX3−CHX2−CHX2−CH=CH(CN)+NaBr\ce{CH3}{-}\allowbreak\ce{CH2}{-}\allowbreak\ce{CH2}{-}\allowbreak\ce{CH}{=}\allowbreak\ce{CHBr} + \ce{NaCN} \mathrel{\ce{->}} \ce{CH3}{-}\allowbreak\ce{CH2}{-}\allowbreak\ce{CH2}{-}\allowbreak\ce{CH}{=}\allowbreak\ce{CH(CN)} + \ce{NaBr}0,2 pts
b.v
CHX3−CH=CH−CHX2−CHX3+CHX3−I→CHX3−CH(CHX3)−CHI−CHX2−CHX3\ce{CH3}{-}\allowbreak\ce{CH}{=}\allowbreak\ce{CH}{-}\allowbreak\ce{CH2}{-}\allowbreak\ce{CH3} + \ce{CH3}{-}\allowbreak\ce{I} \mathrel{\ce{->}} \ce{CH3}{-}\allowbreak\ce{CH(CH3)}{-}\allowbreak\ce{CHI}{-}\allowbreak\ce{CH2}{-}\allowbreak\ce{CH3}0,2 pts